Version 2.0
Date revised: 4/26/2019
SAFETY DATA SHEET
Conforms to regulation (EC) no. EU 453/2010
SECTION 1 - IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1 Product Identifier
1.2 Relevant Identified Uses of the Substance/Mixture and Uses Advised Against
Investigational research by professional users
1.3 Details of the Supplier of the Safety Data Sheet
| Manufacturer National Diagnostics 305 Patton Drive Atlanta, GA 30036 (404) 699-2121 (800) 526-3867 info@nationaldiagnostics.com |
1.4 Emergency Telephone Number
ChemTel Inc.
Contract number MIS8894340
1-800 255-3924 (United States, Canada, Puerto Rico & US Virgin Islands)
01-800-099-0731 (Mexico)
400-120-0751 (China)
000-800-100-4086 (India)
1-300-954-583 (Australia)
0-800-591-6042 (Brazil)
+1-813-255-3924 (All other regions)
SECTION 2 - HAZARDS IDENTIFICATION
2.1 Classification of the Substance or Mixture
Classification according to Regulation (EC) No. 1272/2008 [EU-GHS/CLP]
H225 - Flammable Liquids (Category 2)
H302 - Acute Toxicity-Oral (Category 4)
H371 - Specific Target Organ Toxicity Following Single Exposure (Category 2)
2.2 Label Elements
| GHS Label Elements | ||
 |  | DANGER H225 - Highly flammable liquid and vapor. |
 | ||
2.3 Other Hazards
None found.
SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS
3.2 Mixture
Chemical Names/Description
95% Ethanol 5% Methanol
Component List
| Component | % Comp. | CAS # | EC # | 1278/2008 Classification |
|---|---|---|---|---|
| Methanol | 5 | 67-56-1 | 200-659-6 | H225, H301, H311, H331, H371 |
| Ethanol | 95 | 64-17-5 | 200-578-6 | H225, H319 |
SECTION 4 - FIRST AID MEASURES
4.1 Description of First Aid Measures
Inhalation
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician.
Ingestion
Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Call a physician.
Skin
Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eyes
Immediately flush eyes with plenty of water for at least fifteen minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
4.2 Most Important Symptoms and Effects, Both Acute and Delayed
Inhalation
Methanol:
Irritation of the respiratory tract and mucous membranes. For central nervous system symptoms which may occur due to exposure by inhalation, see Ingestion.
Ethanol:
Cough, drowsiness, headache and fatigue.
Ingestion
Methanol:
Effects may include excitation, euphoria, headache, dizziness, drowsiness, blurred vision, fatigue, tremors, convulsions, loss of consciousness, coma, respiratory arrest and death.
Ethanol:
Burning sensation, confusion. dizziness, headacheand unconsciousness.
Skin
Methanol:
Exposure may cause symptoms similar to those listed under Ingestion.
Ethanol:
Dryness.
Eyes
Methanol:
Irritation, redness, pain, and inflammation.
Ethanol:
Redness, pain and burning.
4.3 Indication of Any Immediate Medical Attention and Special Treatment Needed
Unknown/not applicable
SECTION 5 - FIRE FIGHTING MEASURES
5.1 Extinguishing media
Dry powder, foam, carbon dioxide. (Water may be ineffective.)
5.2 Special Hazards Arising from the Substance/Mixture
Hazardous Combustion Products
Thermal decomposition products may include carbon monoxide, carbon dioxide, and hydrocarbons.
Hazardous Decomposition Products
Carbon dioxide and carbon monoxide may form when heated to decomposition.
Hazardous Polymerization
Will not occur under normal conditions of use (See Sections 10.4 & 10.5).
5.3 Advice for Firefighters
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode.
5.4 Further Information
No data available.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
6.1 Personal Precautions
Wear appropriate protective equipment as specified in Section 8.
6.2 Environmental Precautions
Prevent discharge into the environment. Dike spills and stop leakage where practical. Do not allow material to enter drains.
6.3 Methods and Materials for Containment and Cleaning Up
Eliminate source of ignition. Ventilate area. Cover with absorbent material (soda ash) to confine spill and sweep or shovel into container. Close container tightly. Avoid breathing vapors.
6.4 References to Other Sections
For disposal information see Section 13. For protective clothing and equipment see Section 8.
SECTION 7 - HANDLING AND STORAGE
7.1 Precautions for Safe Handling
Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. Wash thoroughly after handling. Transfer methods should avoid static sparks. Use explosion proof ventilation.
7.2 Conditions for Safe Storage (including any incompatibles)
Keep in a tightly closed container, stored in a cooled, dry, ventilated area away from sources of heat or ignition. Protect from physical damage. Isolate from incompatible materials (section 10).
Incompatibles
Methanol:
Acetyl bromide, calcium carbide, chlorine, chromic anhydride, cyanuric chloride, dichloromethane, diethyl zinc, lead perchlorate, magnesium, metals, strong oxidizers, perchloric acid, phosphorous trioxide, potassium, sodium hypochlorite, sulfuric acid and zinc.
Ethanol:
Strong oxidants, silver salts, acid chlorides, alkali metals, hydrazine, and many other substances.
7.3 Specific End Uses
Investigational research by professional users
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PRECAUTIONS
8.1 Control Parameters
Component: Methanol
ACGIH Threshold Limit Value (TLV):
200 ppm
OSHA Permissable Exposure Limit (PEL):
None established
Component: Ethanol
ACGIH Threshold Limit Value (TLV):
1000 ppm
OSHA Permissable Exposure Limit (PEL):
None established
8.2 Exposure Controls
Engineering Controls
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source.
Respiratory Protection
If the exposure limit is exceeded, wear a supplied air, full-facepiece respirator, airlined hood, or full-facepiece self-contained breathing apparatus.
Eye Protection
Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Skin Protection
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on Basic Physical & Chemical Properties
| a. Appearance | Clear liquid | b. Odor | None |
| c. Odor Threshold | N.A. | d. pH | N.A. |
| e. Melting/Freezing Point (oC) | No Information | f. Boiling point (oC) | 77 |
| g. Flash Point (oC) | 13 | h. Evaporation Rate | 3.3 |
| i. Flammability | Combustible | j. Upper/Lower Flammability or Explosive Limits | lel: 3.3; uel: 19.0 |
| k. Vapor Pressure | 45 @ 20C | l. Vapor Density (Air = 1) | 1.6 |
| m. Relative Density | 0.79 @ 20C/4C | n. Water Solubility | Appreciable (> 10%) |
| o. Partition Coefficient n-octanol/water | log Kow -0.35 | p. Autoignition Temperature (oC) | 463 |
| q. Decomposition Temperature (oC) | Not applicable. | r. Viscosity | No data available. |
| s. Explosive Properties | combustible liquid and vapor | t. Oxidizing Properties | Not an oxidizer |
SECTION 10 - STABILITY AND REACTIVITY
10.1 Reactivity
Combustible. Not reactive under normal conditions of use.
10.2 Chemical Stability
Stable under ordinary conditions of use and storage.
10.3 Possibility of Hazardous Reactions
Will not occur under normal conditions of use (See Sections 10.4 & 10.5).
10.4 Conditions to Avoid
Heat, flames, ignition sources and incompatibles.
10.5 Incompatible Materials
Methanol:
Acetyl bromide, calcium carbide, chlorine, chromic anhydride, cyanuric chloride, dichloromethane, diethyl zinc, lead perchlorate, magnesium, metals, strong oxidizers, perchloric acid, phosphorous trioxide, potassium, sodium hypochlorite, sulfuric acid and zinc.
Ethanol:
Strong oxidants, silver salts, acid chlorides, alkali metals, hydrazine, and many other substances.
10.6 Hazardous Decomposition Products
Carbon dioxide and carbon monoxide may form when heated to decomposition.
SECTION 11 - TOXICOLOGICAL INFORMATION
Product LD50 Values
Oral Rat LD50 (mg/kg)
thyl alcohol: oral rat LD50= 7060; Methyl alcohol: oral rat LD50= 5628
Dermal Rabbit LD50 (mg/kg)
Mehanol skin rabbit LD50= 15800
Component Cancer List Status
| NTP Carcinogen | |||
| Known | Anticipated | IARC Category | |
|---|---|---|---|
| Methanol | No | No | None |
| Ethanol | No | No | None |
Potential Health Effects
Inhalation
Methanol
May irritate the respiratory tract and mucuous membranes. Exposure may cause central nervous system symptoms similar to those listed under Ingestion.
Ethanol
Can cause irritation to the lungs and upper respiratory tract. May cause headache or fatigue.
Ingestion
Methanol
Primary toxic effects are metabolic acidosis and visual system damage. Visual system damage may progress from visual blurring to complete blindness. May cause harmful central nervous system effects which may be delayed.
Ethanol
May cause irritation or central nervous system effects if swallowed.
Skin
Methanol
Absorption from prolonged or massive skin contact may cause poisoning. Repeated or prolonged contact may result in defatting, redness, itching, inflammation, cracking and possible secondary infection. Exposure may cause symptoms similar to those listed under ingestion.
Ethanol
May cause drying or irritation to the skin.
Eyes
Methanol
Exposure to liquid, vapors, fumes or mists may cause irritation. Direct contact may cause irritation, pain, corneal inflammation and possible corneal damage.
Ethanol
May cause irritation to the eyes.
Carcinogenicity
Methanol
This component is not listed as a carcinogen by NTP or IARC.
Ethanol
Not listed as a known or possible carcinogen by NTP or IARC.
Mutagenicity
Methanol
No information available.
Ethanol
No information available.
Reproductive Toxicity
Methanol
Possible reproductive hazard.
Ethanol
Consumption during pregnancy may adversely affect the unborn child.
Teratogenic Effects
Methanol
No information available.
Ethanol
No information available.
Routes of Entry
Methanol
Inhalation, ingestion, or skin contact.
Ethanol
Inhalation, ingestion, skin contact.
Target Organ Statement
Methanol
Chronic intoxication may cause degenerative changes in liver, kidneys, brain, gastrointestinal tract, and heart muscle. Persons with pre-existing liver impairment, skin and respiratory disorders may be at an increased risk from exposure.
Ethanol
Persons with pre-existing skin disorders or eye problems or impaired liver or kidney function may be more susceptible to the effects of the substance.
SECTION 12 - ECOLOGICAL INFOMATION
12.1 Toxicity
COMPONENT: Methanol
| Vertebrates | Invertebrates | Algae | Microorganisms | |
|---|---|---|---|---|
Aquatic Toxicity (ppm unless otherwise noted) | LC50 (96hr, bluegill) 15400 mg/L | EC50 (48 hr, daphnia) > 10000 mg/L | EC50 (96 hr) 22000 mg/L | IC50 (3hr) > 1000 mg/L |
| Birds | Arthropods | Plants | Microorganisms | |
|---|---|---|---|---|
Terrestrial Environment Toxicity (ppm unless otherwise noted) | IC50 (3 day, sativa) 41000 mg/L | No data | No data | No data |
COMPONENT: Ethanol
| Vertebrates | Invertebrates | Algae | Microorganisms | |
|---|---|---|---|---|
Aquatic Toxicity (ppm unless otherwise noted) | LC50 (96 hour, fathead minnow) 14g/L | EC50 (48hr, daphnia) 5g/L | EC50 (72hrs) 275mg/L | IC50 >1g/L |
| Birds | Arthropods | Plants | Microorganisms | |
|---|---|---|---|---|
Terrestrial Environment Toxicity (ppm unless otherwise noted) | No data | No data | EC50 155ppm vapor | No data |
12.2 Persistence and Degradability
Methanol
Readily biodegradable (95% elimination in 20 days)
Ethanol
Readily biodegradable (95% degradation in 15 days)
12.3 Bioaccumulative Potential
Methanol
BCF<10
Ethanol
No data
12.4 Mobility in Soil
Methanol
Koc <1
Ethanol
No data
12.5 Results of PBT and vPvB Assessment
Methanol
not PBT or vPvB
Ethanol
Not PBT or vPvB
12.6 Other Adverse Effects
Methanol
None
Ethanol
None
SECTION 13 - DISPOSAL CONSIDERATIONS
13.1 Waste Treatment Methods
Offer surplus or non-recyclable product to licensed disposal company. Disposal is subject to user compliance with applicable law and product characteristics at time of disposal. Dispose of packaging as product.
SECTION 14 - TRANSPORT INFORMATION
| ADR/RID | IATA | IMO | DOT | |
|---|---|---|---|---|
| 14.1 UN Number | UN1170 | UN1170 | UN1170 | UN1170 |
| 14.2 Shipping Name | ETHANOL SOLUTIONS | ETHANOL SOLUTIONS | ETHANOL SOLUTIONS | ETHANOL SOLUTIONS |
| 14.3 Hazard Class | 3 | 3 | 3 | 3 |
| 14.4 Packing Group | II | II | II | II |
| 14.5 Environmental Hazards | N.A. | N.A. | Not regulated | N.A. |
| 14.6 Special Precautions | N.A. | N.A. | N.A. | N.A. |
SECTION 15 - REGULATORY INFORMATION
15.1 Safety, Health and Environmental Regulations/Legislation Specific for the Substance/Mixture
United States
TSCA Regulatory Statement
All intentional ingredients are listed on the TSCA Inventory.
SARA 311/312 Hazard Categories
| Component | Fire | Pressure | Reactivity | Acute | Chronic |
|---|---|---|---|---|---|
| Methanol | Yes | No | No | Yes | Yes |
| Ethanol | Yes | No | No | Yes | Yes |
Europe
EEC Regulatory
All intentional ingredients are listed on the European EINECS Inventory.
SECTION 16 - OTHER INFORMATION
Revisional Updates
4/26/2019 - Updated Section 1.4
5/29/2015 - Updated Sections 2.1 and 3.2
12/6/2013 - Released Version 1.0
NFPA Codes
Health 1 Flammability 3 Reactivity 0
Dangers
Methanol
H225 - Highly flammable liquid and vapor.
H301 - Toxic if swallowed
H311 - Toxic in contact with skin.
H331 - Toxic if inhaled.
H371 - May cause damage to organs.
Ethanol
H225 - Highly flammable liquid and vapor.
H319 - Causes serious eye irritation.
MANUFACTURER DISCLAIMER: The information given herein is offered in good faith as accurate, but without guarantee. Conditions of the use and suitability of the product for particular uses are beyond our control. All risks of use of the product are therefore assumed by the user. Nothing is intended as a recommendation for uses which infringe valid patents or as extending license under valid patents. Appropriate warnings and safe handling procedures should be provided to handlers and users.