Version 3.0
Date revised: 4/26/2019

SAFETY DATA SHEETNational Diagnostics

Conforms to regulation (EC) no. EU 453/2010

SECTION 1 - IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1 Product Identifier

Product Name: Methylene Bis-Acrylamide Product Number: EC-301

1.2 Relevant Identified Uses of the Substance/Mixture and Uses Advised Against

Investigational research by professional users

1.3 Details of the Supplier of the Safety Data Sheet

Manufacturer
National Diagnostics
305 Patton Drive
Atlanta, GA 30036
(404) 699-2121
(800) 526-3867
info@nationaldiagnostics.com

1.4 Emergency Telephone Number

ChemTel Inc.
Contract number MIS8894340
1-800 255-3924 (United States, Canada, Puerto Rico & US Virgin Islands)
01-800-099-0731 (Mexico)
400-120-0751 (China)
000-800-100-4086 (India)
1-300-954-583 (Australia)
0-800-591-6042 (Brazil)
+1-813-255-3924 (All other regions)

SECTION 2 - HAZARDS IDENTIFICATION

2.1 Classification of the Substance or Mixture

Classification according to Regulation (EC) No. 1272/2008 [EU-GHS/CLP]

H332 - Acute Toxicity-Inhalation (Category 4)

2.2 Label Elements

GHS LABEL ELEMENTS AND CLASSIFICATION
GHS Label Elements
Harmful 

WARNING

H302 - Harmful if swallowed
H332 - Harmful if inhaled.
P261 - Avoid breathing dust/fume/gas/mist/vapors/spray.

  
  

2.3 Other Hazards

None found.

SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Substance

Chemical Names/Description

N, N'-Methylenebisacrylamide, N,N'-methylenebis-2-propenamide


Chemical Formula

C7H10N2O2


Component List

Component % Comp. CAS # EC #
BIS-ACRYLAMIDE100 110-26-9  203-750-9 


SECTION 4 - FIRST AID MEASURES

4.1 Description of First Aid Measures

Inhalation

Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician.

Ingestion

Give large amounts of water to drink. Never give anything by mouth to an unconscious person. Get medical attention.

Skin

Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.

Eyes

Immediately flush eyes with plenty of water for at least fifteen minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

4.2 Most Important Symptoms and Effects, Both Acute and Delayed

Inhalation

Drowsiness, tingling sensations, fatigue, weakness, stumbling, slurred speech, and shaking.

Ingestion

Drowsiness, tingling sensations, fatigue, weakness, stumbling, slurred speech, and shaking.

Skin

Pain and redness. Symptoms of absorption of solutions through the skin may parallel ingestion.

Eyes

Pain and redness.

4.3 Indication of Any Immediate Medical Attention and Special Treatment Needed

Unknown/not applicable

SECTION 5 - FIRE FIGHTING MEASURES

5.1 Extinguishing media

Water spray, dry chemical, alcohol-resistant foam, or carbon dioxide. Do not use high pressure water stream

5.2 Special Hazards Arising from the Substance/Mixture

Hazardous Combustion Products

Carbon monoxide, carbon dioxide, nitrogen oxides.

Hazardous Decomposition Products

Burning may produce carbon monoxide, carbon dioxide, nitrogen oxides.

Hazardous Polymerization

Will not occur under normal conditions of use (See Sections 10.4 & 10.5).

5.3 Advice for Firefighters

In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode.

5.4 Further Information

No data available.

SECTION 6 - ACCIDENTAL RELEASE MEASURES

6.1 Personal Precautions

Wear appropriate protective equipment as specified in Section 8.

6.2 Environmental Precautions

Prevent discharge into the environment. Dike spills and stop leakage where practical. Do not allow material to enter drains.

6.3 Methods and Materials for Containment and Cleaning Up

Ventilate area. Pick up and place in a suitable container for relamation or disposal, using a method that does not generate dust.

6.4 References to Other Sections

For disposal information see Section 13. For protective clothing and equipment see Section 8.

SECTION 7 - HANDLING AND STORAGE

7.1 Precautions for Safe Handling

Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. Wash thoroughly after handling.

7.2 Conditions for Safe Storage (including any incompatibles)

Keep in a tightly closed container, stored in a cooled, dry, ventilated area away from sources of heat or ignition. Protect from physical damage. Isolate from incompatible materials (section 10).

Incompatibles

Strong bases, strong acids, and oxidizing agents.

7.3 Specific End Uses

Investigational research by professional users

SECTION 8 - EXPOSURE CONTROLS/PERSONAL PRECAUTIONS

8.1 Control Parameters

ACGIH Threshold Limit Value (TLV):

5 mg/m3 (TWA) (skin) for solid

OSHA Permissible Exposure Limit (PEL):

None established

8.2 Exposure Controls

Engineering Controls

A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source.

Respiratory Protection

For conditions of use where exposure to the dust or mist is apparent, a full-face dust/mist respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.

Eye Protection

Safety glasses.

Skin Protection

Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.


SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on Basic Physical & Chemical Properties

a. AppearanceFine white crystalsb. OdorNone
c. Odor ThresholdN.A.d. pHNo information found
e. Melting/Freezing Point (oC)>300C (>572F)f. Boiling point (oC)No data found.
g. Flash Point (oC)N.A.h. Evaporation RateNo data found.
i. FlammabilityN.A.j. Upper/Lower Flammability or Explosive LimitsN.A.
k. Vapor PressureNo data found.l. Vapor Density (Air = 1)5.31
m. Relative Density1.24 @ 30Cn. Water SolubilitySlightly soluble
o. Partition Coefficient n-octanol/waterNo Datap. Autoignition Temperature (oC)N.A.
q. Decomposition Temperature (oC)No Datar. ViscosityNo data available.
s. Explosive PropertiesN.A.t. Oxidizing PropertiesN.A.

SECTION 10 - STABILITY AND REACTIVITY

10.1 Reactivity

UV light sensitive

10.2 Chemical Stability

Stable under ordinary conditions of use and storage.

10.3 Possibility of Hazardous Reactions

Will not occur under normal conditions of use (See Sections 10.4 & 10.5).

10.4 Conditions to Avoid

Heat, flames, ignition sources, and incompatibles.

10.5 Incompatible Materials

Strong bases, strong acids, and oxidizing agents.

10.6 Hazardous Decomposition Products

Burning may produce carbon monoxide, carbon dioxide, nitrogen oxides.

SECTION 11 - TOXICOLOGICAL INFORMATION

Product LD50 Values

Oral Rat LD50 (mg/kg)

390

Dermal Rabbit LD50 (mg/kg)

No data.

Component Cancer List Status

 NTP Carcinogen 
 KnownAnticipatedIARC Category
BIS-ACRYLAMIDENoNoNone

Potential Health Effects

Inhalation

Inhalation of mist may cause drowsiness, tingling sensations, fatigue, weakness, stumbling, slurred speech, and shaking. Inhalation studies with this compound have produced acute pulmonary edema in animals. Effects in humans not known.

Ingestion

Toxic! Unsaturated amides cause systemic poisoning.

Skin

Unsaturated amides cause irritation and redness. Solutions may be absorbed through the skin causing systemic poisoning.

Eyes

Contact with the eyes causes irritation.

Carcinogenicity

Not listed as a known or anticipated carcinogen by NTP or IARC.

Mutagenicity

No information available.

Reproductive Toxicity

No information available.

Teratogenic Effects

No information available.

Routes of Entry

Ingestion, inhalation, skin contact.

Target Organ Statement

Persons with pre-existing skin disorders, eye problems, or central or peripheral nervous system conditions may be more susceptible to the effects of this substance.

SECTION 12 - ECOLOGICAL INFOMATION

12.1 Toxicity

 VertebratesInvertebratesAlgaeMicroorganisms
Aquatic Toxicity
(ppm unless otherwise noted)
No dataNo dataNo dataNo data

 BirdsArthropodsPlantsMicroorganisms
Terrestrial Environment Toxicity
(ppm unless otherwise noted)
No dataNo dataNo dataNo data

12.2 Persistence and Degradability

No data

12.3 Bioaccumulative Potential

No data

12.4 Mobility in Soil

No data

12.5 Results of PBT and vPvB Assessment

No data

12.6 Other Adverse Effects

None


SECTION 13 - DISPOSAL CONSIDERATIONS

13.1 Waste Treatment Methods

Offer surplus or non-recyclable product to licensed disposal company. Disposal is subject to user compliance with applicable law and product characteristics at time of disposal. Dispose of packaging as product.


SECTION 14 - TRANSPORT INFORMATION

  ADR/RID IATA IMO DOT
14.1 UN Number Not regulatedNot regulatedNot regulatedNot regulated
14.2 Shipping NameNot regulatedNot regulatedNot regulatedNot regulated
14.3 Hazard ClassNot regulatedNot regulatedNot regulatedNot regulated
14.4 Packing GroupNot regulatedNot regulatedNot regulatedNot regulated
14.5 Environmental HazardsN.A.N.A.Not regulatedN.A.
14.6 Special PrecautionsN.A.N.A.N.A.N.A.

SECTION 15 - REGULATORY INFORMATION

15.1 Safety, Health and Environmental Regulations/Legislation Specific for the Substance/Mixture

United States

TSCA Regulatory Statement

All intentional ingredients are listed on the TSCA Inventory.

SARA 311/312 Hazard Categories
ComponentFirePressureReactivityAcuteChronic
BIS-ACRYLAMIDENoNoNoYesYes

Europe

EEC Regulatory

All intentional ingredients are listed on the European EINECS Inventory.

SECTION 16 - OTHER INFORMATION

Revisional Updates

4/26/2019 - Updated Section 1.4
5/29/2015 - Updated Sections 2.1 and 3.1
5/28/2013 - Released Version 1.0

NFPA Codes

Health 2   Flammability 1  Reactivity 0

MANUFACTURER DISCLAIMER: The information given herein is offered in good faith as accurate, but without guarantee. Conditions of the use and suitability of the product for particular uses are beyond our control. All risks of use of the product are therefore assumed by the user. Nothing is intended as a recommendation for uses which infringe valid patents or as extending license under valid patents. Appropriate warnings and safe handling procedures should be provided to handlers and users.