Version 3.0
Date revised: 4/26/2019
SAFETY DATA SHEET
Conforms to regulation (EC) no. EU 453/2010
SECTION 1 - IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1 Product Identifier
1.2 Relevant Identified Uses of the Substance/Mixture and Uses Advised Against
Investigational research by professional users
1.3 Details of the Supplier of the Safety Data Sheet
| Manufacturer National Diagnostics 305 Patton Drive Atlanta, GA 30036 (404) 699-2121 (800) 526-3867 info@nationaldiagnostics.com |
1.4 Emergency Telephone Number
ChemTel Inc.
Contract number MIS8894340
1-800 255-3924 (United States, Canada, Puerto Rico & US Virgin Islands)
01-800-099-0731 (Mexico)
400-120-0751 (China)
000-800-100-4086 (India)
1-300-954-583 (Australia)
0-800-591-6042 (Brazil)
+1-813-255-3924 (All other regions)
SECTION 2 - HAZARDS IDENTIFICATION
2.1 Classification of the Substance or Mixture
Classification according to Regulation (EC) No. 1272/2008 [EU-GHS/CLP]
H315 - Skin Corrosion/Irritation (Category 2)
H319 - Serious Eye Damage/Eye Irritation (Category 2A)
2.2 Label Elements
| GHS Label Elements | ||
 | WARNING H315 - Causes skin irritation. | |
2.3 Other Hazards
None found.
SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS
3.2 Mixture
Chemical Names/Description
14% solution of sulfuric acid with 1% ammonium ferrous sulfate
Component List
| Component | % Comp. | CAS # | EC # | 1278/2008 Classification |
|---|---|---|---|---|
| SULFURIC ACID | 14 | 7664-93-9 | 231-639-5 | H315, H319 |
| AMMONIUM IRON II SULFATE HEXAHYDRATE | 1 | 7783-85-9 | 233-151-8 | H315, H319, H335 |
SECTION 4 - FIRST AID MEASURES
4.1 Description of First Aid Measures
Inhalation
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician immediately.
Ingestion
DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Call a physician immediately.
Skin
Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Excess acid on skin can be neutralized with a 2% solution of bicarbonate of soda.
Eyes
Immediately flush eyes with gentle but large stream of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Call a physician immediately.
4.2 Most Important Symptoms and Effects, Both Acute and Delayed
Inhalation
SULFURIC ACID:
Inhalation produces damaging effects on the mucous membranes and upper respiratory tract. Symptoms may include irritation of the nose and throat, and labored breathing. May cause lung edema, a medical emergency.
AMMONIUM IRON II SULFATE HEXAHYDRATE:
Coughing, shortness of breath.
Ingestion
SULFURIC ACID:
Corrosive. Swallowing can cause severe burns of the mouth, throat, and stomach, leading to death. Can cause sore throat, vomiting, diarrhea. Circulatory collapse with clammy skin, weak and rapid pulse, shallow respirations, and scanty urine may follow ingestion or skin contact. Circulatory shock is often the immediate cause of death.
AMMONIUM IRON II SULFATE HEXAHYDRATE:
Symptoms may include nausea, vomiting and diarrhea.
Skin
SULFURIC ACID:
Corrosive. Symptoms of redness, pain, and severe burn can occur. Circulatory collapse with clammy skin, weak and rapid pulse, shallow respirations, and scanty urine may follow skin contact or ingestion. Circulatory shock is often the immediate cause of death.
AMMONIUM IRON II SULFATE HEXAHYDRATE:
Redness, itching, and pain.
Eyes
SULFURIC ACID:
Corrosive. Contact can cause blurred vision, redness, pain and severe tissue burns. Can cause blindness.
AMMONIUM IRON II SULFATE HEXAHYDRATE:
Irritation, redness, and pain.
4.3 Indication of Any Immediate Medical Attention and Special Treatment Needed
Unknown/not applicable
SECTION 5 - FIRE FIGHTING MEASURES
5.1 Extinguishing media
Dry chemical, foam or carbon dioxide. Do not use water on material. However, water spray may be used to keep fire exposed containers cool.
5.2 Special Hazards Arising from the Substance/Mixture
Hazardous Combustion Products
Contact with most metals causes formation of flammable and explosive hydrogen gas.
Hazardous Decomposition Products
Toxic fumes of oxides of sulfur when heated to decomposition. Will react with water or steam to produce toxic and corrosive fumes. Reacts with carbonates to generate carbon dioxide gas, and with cyanides and sulfide to form poisonous hydrogen cyanide and hydrogen sulfide respectively.
Hazardous Polymerization
Will not occur under normal conditions of use (See Sections 10.4 & 10.5).
5.3 Advice for Firefighters
Full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in positive pressure mode. Structural firefighter's protective clothing is ineffective for fires
5.4 Further Information
No data available.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
6.1 Personal Precautions
Wear appropriate protective equipment as specified in Section 8.
6.2 Environmental Precautions
Prevent discharge into the environment. Dike spills and stop leakage where practical. Do not allow material to enter drains.
6.3 Methods and Materials for Containment and Cleaning Up
Ventilate area. Wear personal protective equipment as specified in Section 8. Isolate hazard area. Neutralize material with dry lime or soda ash, absorb with inert material (vermiculite, sand), keep in a closed container and hold for waste disposal.
6.4 References to Other Sections
For disposal information see Section 13. For protective clothing and equipment see Section 8.
SECTION 7 - HANDLING AND STORAGE
7.1 Precautions for Safe Handling
Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. Wash thoroughly after handling. Wear special protective equipment (Sec. 8) where exposures may exceed established levels.
7.2 Conditions for Safe Storage (including any incompatibles)
Store in a cool, dry, ventilated storage area with acid resistant floors and good drainage. Protect from physical damage. Keep out of direct sunlight and away from heat, water, and incompatible materials.
Incompatibles
SULFURIC ACID:
Acetic Anhydride, Acetone Cyanhydrin, Acetone + Nitric Acid, Acetone + Potassium Dichromate, Acetonitrile, Acrolein, Acrylonitrile, Alcohols + Hydrogen Peroxide, Allyl Alcohol, Allyl Chloride, 2-Aminoethanol, Ammonium Hydroxide, Ammonium Triperchromate, Aniline, Bromates + Metals, Bromine Pentafluoride, n-Butyraldehyde, Carbides, Cesium Acetylene Carbide, Chlorates, Chlorine Trifluoride, Chlorosulfonic Acid, Cuprous Nitride, Diisobutylene, Epichlorohydrin, Ethylene Cyanohydrin, Ethylene Diamine, Ethylene Glycol, Ethylenimine, Fulminates, Other Acids, Iodine Heptafluoride, Metals, Isoprene, Lithium Silicide, Mercuric Nitride, Mesityl Oxide, P-Nitrotoluene, Pentasilver Trihydroxydiaminophosphate, Perchlorates, Permanganates + Benzene, Phosphorus, Phosphorus Isocyanate, Picrates, Potassium t-Butoxide, Potassium Chlorate, Permanganates, beta-Propiolactone, Propylene Oxide, Pyridine, Rubidium Acetylene Carbide and Sodium.
AMMONIUM IRON II SULFATE HEXAHYDRATE:
Strong oxidizing agents.
7.3 Specific End Uses
Investigational research by professional users
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PRECAUTIONS
8.1 Control Parameters
Component: SULFURIC ACID
ACGIH Threshold Limit Value (TLV):
1 mg/m3 TWA 15 mg/m3 IDLH
OSHA Permissable Exposure Limit (PEL):
1 mg/m3 TWA
Component: AMMONIUM IRON II SULFATE HEXAHYDRATE
ACGIH Threshold Limit Value (TLV):
1 mg/m3 (TWA)
OSHA Permissable Exposure Limit (PEL):
None established
8.2 Exposure Controls
Engineering Controls
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source.
Respiratory Protection
If the exposure limit is exceeded and engineering controls are not feasible, a full facepiece respirator with an acid gas cartridge and particulate filter (NIOSH type N100 filter) may be worn up to 50 times the exposure limit.
Eye Protection
Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Skin Protection
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on Basic Physical & Chemical Properties
| a. Appearance | Clear colorless solution | b. Odor | None |
| c. Odor Threshold | N.A. | d. pH | <1 |
| e. Melting/Freezing Point (oC) | -7 | f. Boiling point (oC) | 106 |
| g. Flash Point (oC) | N.A. | h. Evaporation Rate | No data |
| i. Flammability | N.A. | j. Upper/Lower Flammability or Explosive Limits | NA |
| k. Vapor Pressure | 1 @ 145.8C | l. Vapor Density (Air = 1) | 3.4 |
| m. Relative Density | 1.1 | n. Water Solubility | Miscible with water |
| o. Partition Coefficient n-octanol/water | mixture | p. Autoignition Temperature (oC) | N.A. |
| q. Decomposition Temperature (oC) | Not applicable. | r. Viscosity | No data available. |
| s. Explosive Properties | N.A. | t. Oxidizing Properties | Contains sulfuric acid |
SECTION 10 - STABILITY AND REACTIVITY
10.1 Reactivity
Strong acid solution- will react violently with alkali. Oxidizer- will react with reductants, will corrode metals.
10.2 Chemical Stability
Stable under recommended conditions of use and storage.
10.3 Possibility of Hazardous Reactions
Will not occur under normal conditions of use (See Sections 10.4 & 10.5).
10.4 Conditions to Avoid
Heat, moisture, incompatibles.
10.5 Incompatible Materials
SULFURIC ACID:
Acetic Anhydride, Acetone Cyanhydrin, Acetone + Nitric Acid, Acetone + Potassium Dichromate, Acetonitrile, Acrolein, Acrylonitrile, Alcohols + Hydrogen Peroxide, Allyl Alcohol, Allyl Chloride, 2-Aminoethanol, Ammonium Hydroxide, Ammonium Triperchromate, Aniline, Bromates + Metals, Bromine Pentafluoride, n-Butyraldehyde, Carbides, Cesium Acetylene Carbide, Chlorates, Chlorine Trifluoride, Chlorosulfonic Acid, Cuprous Nitride, Diisobutylene, Epichlorohydrin, Ethylene Cyanohydrin, Ethylene Diamine, Ethylene Glycol, Ethylenimine, Fulminates, Other Acids, Iodine Heptafluoride, Metals, Isoprene, Lithium Silicide, Mercuric Nitride, Mesityl Oxide, P-Nitrotoluene, Pentasilver Trihydroxydiaminophosphate, Perchlorates, Permanganates + Benzene, Phosphorus, Phosphorus Isocyanate, Picrates, Potassium t-Butoxide, Potassium Chlorate, Permanganates, beta-Propiolactone, Propylene Oxide, Pyridine, Rubidium Acetylene Carbide and Sodium.
AMMONIUM IRON II SULFATE HEXAHYDRATE:
Strong oxidizing agents.
10.6 Hazardous Decomposition Products
Toxic fumes of oxides of sulfur when heated to decomposition. Will react with water or steam to produce toxic and corrosive fumes. Reacts with carbonates to generate carbon dioxide gas, and with cyanides and sulfide to form poisonous hydrogen cyanide and hydrogen sulfide respectively.
SECTION 11 - TOXICOLOGICAL INFORMATION
Product LD50 Values
Oral Rat LD50 (mg/kg)
2140
Dermal Rabbit LD50 (mg/kg)
No data.
Component Cancer List Status
| NTP Carcinogen | |||
| Known | Anticipated | IARC Category | |
|---|---|---|---|
| SULFURIC ACID | Yes | Yes | 1 |
| AMMONIUM IRON II SULFATE HEXAHYDRATE | No | No | None |
Potential Health Effects
Inhalation
SULFURIC ACID
Harmful if inhaled. May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract.
AMMONIUM IRON II SULFATE HEXAHYDRATE
Causes irritation to the respiratory tract. Symptoms may include coughing, shortness of breath.
Ingestion
SULFURIC ACID
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns.
AMMONIUM IRON II SULFATE HEXAHYDRATE
Causes irritation to the gastrointestinal tract. Symptoms may include nausea, vomiting and diarrhea. Low toxicity in small quantities but larger dosages may cause nausea, vomiting, diarrhea, and black stool. Pink urine discoloration is a strong indicator of iron poisoning. Liver damage, coma, and death from iron poisoning has been recorded.
Skin
SULFURIC ACID
Causes skin burns.
AMMONIUM IRON II SULFATE HEXAHYDRATE
Causes irritation to skin. Symptoms include redness, itching, and pain.
Eyes
SULFURIC ACID
Causes severe eye burns. May cause irreversible eye injury.
AMMONIUM IRON II SULFATE HEXAHYDRATE
Causes irritation, redness, and pain.
Carcinogenicity
SULFURIC ACID
Chronic exposure to mists containing sulfuric acid is a cancer hazard. Cancer Status: The International Agency for Research on Cancer (IARC) has classified strong inorganic acid mists containing sulfuric acid as a known human carcinogen, (IARC category 1). This classification applies only to mists containing sulfuric acid and not to sulfuric acid or sulfuric acid solutions.
AMMONIUM IRON II SULFATE HEXAHYDRATE
Not listed as a known or anticipated carcinogen by NTP or IARC.
Mutagenicity
SULFURIC ACID
No information found.
AMMONIUM IRON II SULFATE HEXAHYDRATE
No information found.
Reproductive Toxicity
SULFURIC ACID
No information found.
AMMONIUM IRON II SULFATE HEXAHYDRATE
No information found.
Teratogenic Effects
SULFURIC ACID
No information found.
AMMONIUM IRON II SULFATE HEXAHYDRATE
No information found.
Routes of Entry
SULFURIC ACID
Ingestion, Inhalation, or through the skin.
AMMONIUM IRON II SULFATE HEXAHYDRATE
Ingestion, Inhalation, or through the skin.
Target Organ Statement
SULFURIC ACID
No information found.
AMMONIUM IRON II SULFATE HEXAHYDRATE
No information found.
SECTION 12 - ECOLOGICAL INFOMATION
12.1 Toxicity
COMPONENT: SULFURIC ACID
| Vertebrates | Invertebrates | Algae | Microorganisms | |
|---|---|---|---|---|
Aquatic Toxicity (ppm unless otherwise noted) | LC50(96 hr, bluegill) pH 3.5 | EC50 (daphnia) >100mg/L | EC50 (72hr) >100mg/L | NOEC (3 hrs) >180mg/L |
| Birds | Arthropods | Plants | Microorganisms | |
|---|---|---|---|---|
Terrestrial Environment Toxicity (ppm unless otherwise noted) | No data | No data | No data | No data |
COMPONENT: AMMONIUM IRON II SULFATE HEXAHYDRATE
| Vertebrates | Invertebrates | Algae | Microorganisms | |
|---|---|---|---|---|
Aquatic Toxicity (ppm unless otherwise noted) | No data | No data | No data | No data |
| Birds | Arthropods | Plants | Microorganisms | |
|---|---|---|---|---|
Terrestrial Environment Toxicity (ppm unless otherwise noted) | No data | No data | No data | No data |
12.2 Persistence and Degradability
SULFURIC ACID
No data
AMMONIUM IRON II SULFATE HEXAHYDRATE
No data
12.3 Bioaccumulative Potential
SULFURIC ACID
No data
AMMONIUM IRON II SULFATE HEXAHYDRATE
No data
12.4 Mobility in Soil
SULFURIC ACID
No data
AMMONIUM IRON II SULFATE HEXAHYDRATE
No data
12.5 Results of PBT and vPvB Assessment
SULFURIC ACID
Not PBT or vPvB
AMMONIUM IRON II SULFATE HEXAHYDRATE
No data
12.6 Other Adverse Effects
SULFURIC ACID
None
AMMONIUM IRON II SULFATE HEXAHYDRATE
None
SECTION 13 - DISPOSAL CONSIDERATIONS
13.1 Waste Treatment Methods
Offer surplus or non-recyclable product to licensed disposal company. Disposal is subject to user compliance with applicable law and product characteristics at time of disposal. Dispose of packaging as product.
SECTION 14 - TRANSPORT INFORMATION
| ADR/RID | IATA | IMO | DOT | |
|---|---|---|---|---|
| 14.1 UN Number | N.A. | N.A. | N.A. | N.A. |
| 14.2 Shipping Name | N.A | N.A | N.A | N.A |
| 14.3 Hazard Class | N.A. | N.A. | N.A. | N.A. |
| 14.4 Packing Group | N.A. | N.A. | N.A. | N.A. |
| 14.5 Environmental Hazards | N.A. | N.A. | Not regulated | N.A. |
| 14.6 Special Precautions | N.A. | N.A. | N.A. | N.A. |
SECTION 15 - REGULATORY INFORMATION
15.1 Safety, Health and Environmental Regulations/Legislation Specific for the Substance/Mixture
United States
TSCA Regulatory Statement
All intentional ingredients are listed on the TSCA Inventory.
SARA 311/312 Hazard Categories
| Component | Fire | Pressure | Reactivity | Acute | Chronic |
|---|---|---|---|---|---|
| SULFURIC ACID | No | No | Yes | Yes | Yes |
| AMMONIUM IRON II SULFATE HEXAHYDRATE | No | No | No | Yes | No |
Europe
EEC Regulatory
All intentional ingredients are listed on the European EINECS Inventory.
SECTION 16 - OTHER INFORMATION
Revisional Updates
4/26/2019 - Updated Section 1.4
5/29/2015 - Updated Sections 2.1 and 3.2
11/21/2013 - Updated Sections 2, 3 and 14
5/29/2013 - Released Version 1.0
NFPA Codes
Health 2 Flammability 0 Reactivity 2
Dangers
SULFURIC ACID
H315 - Causes skin irritation.
H319 - Causes serious eye irritation.
AMMONIUM IRON II SULFATE HEXAHYDRATE
H315 - Causes skin irritation.
H319 - Causes serious eye irritation.
H335 - May cause respiratory irritation.
MANUFACTURER DISCLAIMER: The information given herein is offered in good faith as accurate, but without guarantee. Conditions of the use and suitability of the product for particular uses are beyond our control. All risks of use of the product are therefore assumed by the user. Nothing is intended as a recommendation for uses which infringe valid patents or as extending license under valid patents. Appropriate warnings and safe handling procedures should be provided to handlers and users.